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The Ruger Alaskan 454 Casul/45 long Colt is the best for this purpose because it was designed strictly for that purpose!

This pistol being short and double action along with full house 454 ammo it can be used even when under a big brown bear without haveing to cock it between shots or having a long barrel get in the way. A big grizz or brownie at charging range simply doesn't need more barrel than is absolutely necessary, but power it does need!