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Thats right shot placement is king but if you can put a big bullet where it has to go would that not be the best of two worlds??

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Correct.

If one misses the charging elephants brain with a minimal degree one is probably killed. Missing by the same amount with a 500 the elephant is probably flattened.

Irrespective on how "quick A PH says one calibre kills with a brain shot vs another also with a brain shot.